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#1
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Are Paper Speeds Slow Due to the Thin Emulsion?
At least according to conventional wisdom slow films have thin
emulsions and fast films have thick emulsions. I know from tests done that a 120 roll of slow Pan F+ has much more silver content than an equivalent area of print paper. I do not know a paper's film equivalent ISO but the Pan F+ ISO is likely 6 to 10 times greater. Mr. Knoppow has mentioned the extreme fine grain of paper emulsions. In itself that supports the idea of papers having thin emulsions. In fact IIRC, he has compared very slow micofilm emulsions to print paper emulsions. I suggest that paper is slow because it has a very thin emulsion and little silver. I'd like to know more of the relationship because I'm about to do some film developer tests using print paper. I think the correspondence may be great thereby making for valid tests. I'm hoping some others will shed more light. Dan |
#2
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Are Paper Speeds Slow Due to the Thin Emulsion?
"Dan Quinn" wrote in message
om... [...] I'd like to know more of the relationship because I'm about to do some film developer tests using print paper. I think the correspondence may be great thereby making for valid tests. Print developer for printing paper? May I ask why? |
#3
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Are Paper Speeds Slow Due to the Thin Emulsion?
"Dan Quinn" wrote in message
om... [...] I'd like to know more of the relationship because I'm about to do some film developer tests using print paper. I think the correspondence may be great thereby making for valid tests. Print developer for printing paper? May I ask why? |
#5
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Print papers are obviously slow, because it is desirable to enable burning dodging and other print controls. The speed of papers are typically the result of two factors content-amount of bromide & content amount of chloride. Every paper could have the same content of silver and granularity, but if you vary chloride and bromide you will have very different results, some slower some faster depending on the proportions. In article , (Dan Quinn) wrote: At least according to conventional wisdom slow films have thin emulsions and fast films have thick emulsions. I know from tests done that a 120 roll of slow Pan F+ has much more silver content than an equivalent area of print paper. I do not know a paper's film equivalent ISO but the Pan F+ ISO is likely 6 to 10 times greater. Mr. Knoppow has mentioned the extreme fine grain of paper emulsions. In itself that supports the idea of papers having thin emulsions. In fact IIRC, he has compared very slow micofilm emulsions to print paper emulsions. I suggest that paper is slow because it has a very thin emulsion and little silver. I'd like to know more of the relationship because I'm about to do some film developer tests using print paper. I think the correspondence may be great thereby making for valid tests. I'm hoping some others will shed more light. Dan -- LF Website @ http://members.verizon.net/~gregoryblank "To announce that there must be no criticism of the President, or that we are to stand by the President, right or wrong, is not only unpatriotic and servile, but is morally treasonable to the American public."--Theodore Roosevelt, May 7, 1918 |
#6
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Are Paper Speeds Slow Due to the Thin Emulsion?
"Dan Quinn" wrote in message om... At least according to conventional wisdom slow films have thin emulsions and fast films have thick emulsions. I know from tests done that a 120 roll of slow Pan F+ has much more silver content than an equivalent area of print paper. I do not know a paper's film equivalent ISO but the Pan F+ ISO is likely 6 to 10 times greater. Mr. Knoppow has mentioned the extreme fine grain of paper emulsions. In itself that supports the idea of papers having thin emulsions. In fact IIRC, he has compared very slow micofilm emulsions to print paper emulsions. I suggest that paper is slow because it has a very thin emulsion and little silver. I'd like to know more of the relationship because I'm about to do some film developer tests using print paper. I think the correspondence may be great thereby making for valid tests. I'm hoping some others will shed more light. Dan The conventional wisdom is wrong. Emulsion speed has nothing to do with thickness. It is mainly a function of the way the emulsion is made and sensitized. There are so many factors affecting speed that its difficult to name them all but the more important ones are the kind of silver halide used (Silver Iodide is fastest and is usually combined with Silver bromide in film), the exact way the halides are injected into the gelatin, this affects the crystal shape. The way the emulsion is ripened and how many ripenings it gets. Also very important are trace materials added to the emulsion. Certain metals increase speed, Gold is an important one but cadmium and others are also used. Silver halide is sensitive to blue and near UV light. Silver Iodide to blue green. To sensitize the film to other colors dyes or combinations of dyes are added. Other ingredients of the emulsion also affect speed. These include silver sulfide and ammonia. High speed emulsons also reqire effective anti-fog agents and stabilizers. Paper emulsions are made from (usually) a mixture of Silver Chloride and Silver Bromide. Variable contrast paper probably has some Silver iodide in it as well. The emulsions are made differently. They are ripened less and are washed differently. They may not contain some of the sensitizing agents found in film. Paper emulsion is thin because it does not have to be thick to get sufficient density. This is because the light must go through it twice. Film emulsion is not that thick either. In the past many films were double coated with a fast emulion and a slower one of different contrasts. This extended the exposure range of the film. Modern emulsion making technique allows equally great latitude with a single coating. The coating can also be thinner. In a film this has the advantage that there is less spreading out of light within the emulsion. This spreading, due to scattering from the halide particals, is called irradiation. Its effect is to limit resolution and sharpness. The thinne the emulsion the better for sharpness but at some point the film will become limited as to density range. Double coated films are still made but even those have thinner coatings than in the past. Color films by their nature must have several coatings. Much of the technology of thin coatings now applied to Black-and-White film comes from research into color films. Much of the conventional wisdom about emulsions is just plain wrong. The idea that paper must be "silver rich" to have dense blacks or good tonal range is myth. So are the similar ideas about film. The performance of film or paper has very little do to with the amount of silver in it. -- --- Richard Knoppow Los Angeles, CA, USA |
#7
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Are Paper Speeds Slow Due to the Thin Emulsion?
"Dan Quinn" wrote in message om... At least according to conventional wisdom slow films have thin emulsions and fast films have thick emulsions. I know from tests done that a 120 roll of slow Pan F+ has much more silver content than an equivalent area of print paper. I do not know a paper's film equivalent ISO but the Pan F+ ISO is likely 6 to 10 times greater. Mr. Knoppow has mentioned the extreme fine grain of paper emulsions. In itself that supports the idea of papers having thin emulsions. In fact IIRC, he has compared very slow micofilm emulsions to print paper emulsions. I suggest that paper is slow because it has a very thin emulsion and little silver. I'd like to know more of the relationship because I'm about to do some film developer tests using print paper. I think the correspondence may be great thereby making for valid tests. I'm hoping some others will shed more light. Dan The conventional wisdom is wrong. Emulsion speed has nothing to do with thickness. It is mainly a function of the way the emulsion is made and sensitized. There are so many factors affecting speed that its difficult to name them all but the more important ones are the kind of silver halide used (Silver Iodide is fastest and is usually combined with Silver bromide in film), the exact way the halides are injected into the gelatin, this affects the crystal shape. The way the emulsion is ripened and how many ripenings it gets. Also very important are trace materials added to the emulsion. Certain metals increase speed, Gold is an important one but cadmium and others are also used. Silver halide is sensitive to blue and near UV light. Silver Iodide to blue green. To sensitize the film to other colors dyes or combinations of dyes are added. Other ingredients of the emulsion also affect speed. These include silver sulfide and ammonia. High speed emulsons also reqire effective anti-fog agents and stabilizers. Paper emulsions are made from (usually) a mixture of Silver Chloride and Silver Bromide. Variable contrast paper probably has some Silver iodide in it as well. The emulsions are made differently. They are ripened less and are washed differently. They may not contain some of the sensitizing agents found in film. Paper emulsion is thin because it does not have to be thick to get sufficient density. This is because the light must go through it twice. Film emulsion is not that thick either. In the past many films were double coated with a fast emulion and a slower one of different contrasts. This extended the exposure range of the film. Modern emulsion making technique allows equally great latitude with a single coating. The coating can also be thinner. In a film this has the advantage that there is less spreading out of light within the emulsion. This spreading, due to scattering from the halide particals, is called irradiation. Its effect is to limit resolution and sharpness. The thinne the emulsion the better for sharpness but at some point the film will become limited as to density range. Double coated films are still made but even those have thinner coatings than in the past. Color films by their nature must have several coatings. Much of the technology of thin coatings now applied to Black-and-White film comes from research into color films. Much of the conventional wisdom about emulsions is just plain wrong. The idea that paper must be "silver rich" to have dense blacks or good tonal range is myth. So are the similar ideas about film. The performance of film or paper has very little do to with the amount of silver in it. -- --- Richard Knoppow Los Angeles, CA, USA |
#8
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Are Paper Speeds Slow Due to the Thin Emulsion?
In article ,
"Richard Knoppow" wrote: Much of the conventional wisdom about emulsions is just plain wrong. The idea that paper must be "silver rich" to have dense blacks or good tonal range is myth. So are the similar ideas about film. The performance of film or paper has very little do to with the amount of silver in it. Matter of fact once those newer emulsions are calibrated for use, they prove superior imop to thicker emulsions least for sharpness of detail. -- LF Website @ http://members.verizon.net/~gregoryblank "To announce that there must be no criticism of the President, or that we are to stand by the President, right or wrong, is not only unpatriotic and servile, but is morally treasonable to the American public."--Theodore Roosevelt, May 7, 1918 |
#9
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Are Paper Speeds Slow Due to the Thin Emulsion?
"jjs" wrote in message
... Print developer for printing paper? May I ask why? Silly me. I meant "Film developer for printing paper?". |
#10
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Are Paper Speeds Slow Due to the Thin Emulsion?
In article ,
"jjs" wrote: "jjs" wrote in message ... Print developer for printing paper? May I ask why? Silly me. I meant "Film developer for printing paper?". Too much alcohol ah? Besides were you not in your own killfile,.... time to put your self back in. LOL. |
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